Fischer, Malte and Schmidtmann, Marc and Beckhaus, Rüdiger (2018) Crystal structure of the η4-ketimine titanium complex (diphenylamido-κN){3-methyl-6-[(4-methylphenyl)(phenylazanidyl)methylidene]cyclohexa-2,4-dien-1-yl-κ2 N,C 1}(η5-pentamethylcyclopentadienyl)titanium(IV). Acta Crystallographica Section E Crystallographic Communications, 74 (1). pp. 34-37. ISSN 2056-9890

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Abstract

The mol­ecular structure of the title titanium(IV) half-sandwich complex, [Ti(η5-C10H15)(η4-C21H19N)(C12H10N)], shows a three-legged piano-stool geometry at the central TiIV atom, comprising of one penta­methyl­cyclo­penta­dienyl ligand, one bidentate ketimine ligand in an η4-coordination mode and one monodentate di­phenyl­amide ligand. Except for van der Waals forces, there are no significant inter­molecular inter­actions in the crystal.

Item Type:	Article
Additional Information:	Publiziert mit Hilfe des DFG-geförderten Open Access-Publikationsfonds der Carl von Ossietzky Universität Oldenburg.
Uncontrolled Keywords:	crystal structure; titanium; η4-ketimine complex; half-sandwich complex
Subjects:	Science and mathematics > Chemistry
Divisions:	Faculty of Mathematics and Science > Department of Chemistry (IfC)
Date Deposited:	15 Feb 2018 14:57
Last Modified:	15 Feb 2018 14:57
URI:	https://oops.uni-oldenburg.de/id/eprint/3502
URN:	urn:nbn:de:gbv:715-oops-35837
DOI:	doi:10.1107/S2056989017017455
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