Rattanawongsa, Wachiraya and Rößner, Frank and Wittayakun, Jatuporn (2020) Preparation of cerium-impregnated zeolite NaY and investigation of surface acid-base by catalytic transformation of methylbutynol. IVCST 2020: conference proceedings, SUT International Virtual Conference on Science and Technology, 28th August 2020, at Suranaree University of Technology, Nakhon-Ratchasima, Thailand. pp. 369-375.

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Abstract

Cerium on zeolite NaY was prepared by incipient wetness impregnation (Ce-NaY-IMP). Upon calcination, CeO2 species is generated, as confirmed by Raman and DR UV-Vis spectroscopy. The investigation of acid-base properties by the transformation of methylbutynol (MBOH) revealed that Ce-NaY-IMP enhanced only the selectivity of basic pathway products. The impregnation increased Lewis basic sites from oxygen vacancies within CeO2 lattice. In addition, the basicity of Ce-NaY-IMP suppressed the acidity or charge compensating cations sites of parent NaY.

Item Type:	Article
Uncontrolled Keywords:	Zeolite Y, Impregnation, Acid-Base, Cerium oxide, Methylbutynol
Subjects:	Technology, medicine, applied sciences > Chemical engineering
Divisions:	Faculty of Mathematics and Science > Department of Chemistry (IfC)
Date Deposited:	01 Apr 2022 11:36
Last Modified:	01 Apr 2022 11:36
URI:	https://oops.uni-oldenburg.de/id/eprint/5275
URN:	urn:nbn:de:gbv:715-oops-53566
DOI:
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