Zielinski, Oliver and Rüssmeier, Nick and Ferdinand, Oliver D. and Miranda, Mario L. and Wollschläger, Jochen (2018) Assessing fluorescent organic matter in natural waters: towards in situ excitation–emission matrix spectroscopy. Applied Sciences, 8 (12). p. 2685. ISSN 2076-3417

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Official URL: http://dx.doi.org/10.3390/app8122685

Abstract

Natural organic matter (NOM) is a key parameter in aquatic biogeochemical processes. Part of the NOM pool exhibits optical properties, namely absorption and fluorescence. The latter is frequently utilized in laboratory measurements of its dissolved fraction (fluorescent dissolved organic matter, FDOM) through excitation–emission matrix spectroscopy (EEMS). We present the design and field application of a novel EEMS sensor system applicable in situ, the ‘Kallemeter’. Observations are based on a field campaign, starting in Norwegian coastal waters entering the Trondheimsfjord. Comparison against the bulk fluorescence of two commercial FDOM sensors exhibited a good correspondence of the different methods and the ability to resolve gradients and dynamics along the transect. Complementary laboratory EEM spectra measurements of surface water samples and their subsequent PARAFAC analysis revealed three dominant components while the ‘Kallemeter’ EEMS sensor system was able to produce reasonable EEM spectra in high DOM concentrated water bodies, yet high noise levels must be addressed in order to provide comparable PARAFAC components. Achievements and limitations of this proof-of-concept are discussed providing guidance towards full in situ EEMS measurements to resolve rapid changes and processes in natural waters based on the assessment of spectral properties. Their combination with multiwavelength FDOM sensors onboard autonomous platforms will enhance our capacities in observing biogeochemical processes in the marine environment in spatiotemporal and spectral dimensions.

Item Type: Article
Additional Information: Publiziert mit Hilfe des DFG-geförderten Open Access-Publikationsfonds der Carl von Ossietzky Universität Oldenburg.
Uncontrolled Keywords: natural organic matter; DOM; FDOM; CDOM; Gelbstoff; EEMS; PARAFAC; marine sensors; Kallemeter; FerryBox; Trondheimsfjord; Norway
Subjects: Science and mathematics > Life sciences, biology
Divisions: Faculty of Mathematics and Science > Institute for Chemistry and Biology of the Marine Environment (ICBM)
Date Deposited: 12 Sep 2019 11:31
Last Modified: 13 Sep 2019 09:23
URI: https://oops.uni-oldenburg.de/id/eprint/4165
URN: urn:nbn:de:gbv:715-oops-42465
DOI: doi:10.3390/app8122685
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