Fangmann, Pia and Schmidtmann, Marc and Beckhaus, Rüdiger (2018) Crystal structures of 2,3,8,9,14,15-hexamethyl-5,6,11,12,17,18-hexaazatrinaphthylene and 2,3,8,9,14,15-hexaphenyl-5,6,11,12,17,18-hexazatrinaphthylene dichloromethane disolvate. Acta crystallographica. Section E. Crystallographic communications, 74 (2). pp. 167-171. ISSN 2056-9890

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The crystal structures of two substituted HATN (hexa­aza­tri­naphthyl­ene) derivatives, namely 2,3,8,9,14,15-hexa­methyl- and 2,3,8,9,14,15-hexa­phenyl-5,6,11,12,17,18- hexa­zatri­naphthyl­ene (HATNMe6 and HATNPh6), are reported. Whereas the structure of the methyl-substituted derivative (HATNMe6) contains no solvent mol­ecules (C30H24N6), the hexa­phenyl-substituted structure (HATNPh6) contains two mol­ecules of di­chloro­methane (C60H36N6·2CH2Cl2). This class of planar bridging ligands is known for its electron-deficient systems and its ability to form π–π stacking inter­actions. Indeed, in both crystal structures strong π–π stacking inter­actions are observed, but with different packing features. The di­chloro­methane mol­ecules in the crystal structure of HATNPh6 are situated in the voids and are involved in C—H...N contacts to the nitro­gen atoms of the pyrazine units.

Item Type: Article
Additional Information: Publiziert mit Hilfe des DFG-geförderten Open Access-Publikationsfonds der Carl von Ossietzky Universität Oldenburg
Uncontrolled Keywords: crystal structure; N-heterocycles; multidentate ligand; π–π stacking
Subjects: Science and mathematics > Chemistry
Divisions: Faculty of Mathematics and Science > Department of Chemistry (IfC)
Date Deposited: 02 Aug 2018 06:56
Last Modified: 09 Aug 2018 10:36
URN: urn:nbn:de:gbv:715-oops-37527
DOI: 10.1107/S2056989018000725

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